665096
三氯氧代 [（二甲基硫醚）三苯基膦氧化物] 铼 (V)
97%, powder
别名:
Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
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关于此项目
经验公式（希尔记法）:
C20H21Cl3O2PReS
化学文摘社编号:
分子量:
648.98
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
三氯氧代 [（二甲基硫醚）三苯基膦氧化物] 铼 (V), 97%
Quality Segment
assay
97%
form
powder
reaction suitability
core: rhenium, reagent type: catalyst
SMILES string
CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
InChI key
GIBDGLAUIKUJJX-UHFFFAOYSA-K
Application
Catalyst for:
Reactant for synthesis of mono and dinuclear compounds
Reagent for rhenium-cyclized somatostatine derivative series synthesis
- Enantioselective reduction of ketones and imines
- Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
- Synthesis of 2-deoxy-α glycosides
- Sulfurization of phosphorous(III) compounds with thiiranes
Reactant for synthesis of mono and dinuclear compounds
Reagent for rhenium-cyclized somatostatine derivative series synthesis
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves