665797
(S)-(−)-3,3,3-Trifluoro-1,2-epoxypropane
97%
Synonym(s):
(S)-(−)-2-(Trifluoromethyl)oxirane
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About This Item
Empirical Formula (Hill Notation):
C3H3F3O
CAS Number:
Molecular Weight:
112.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
97%
InChI
1S/C3H3F3O/c4-3(5,6)2-1-7-2/h2H,1H2/t2-/m0/s1
SMILES string
FC(F)(F)[C@@H]1CO1
InChI key
AQZRARFZZMGLHL-REOHCLBHSA-N
assay
97%
refractive index
n20/D <1.300
bp
25-32 °C
density
1.294 g/mL at 25 °C
functional group
ether, fluoro
storage temp.
−20°C
Quality Level
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Application
Precursor to a trifluoromethyl chiral auxiliary which promotes a highly diastereoselective Simmons-Smith cyclopropanation.
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Tetrahedron Asymmetry, 17, 1157-1157 (2006)
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