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667811

(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane

Name: (−)-1,2-Bis((2<I>R</I>,5<I>R</I>)-2,5-diphenylphospholano)ethane
Brand: ALDRICH

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About This Item

Empirical Formula (Hill Notation):

C₃₄H₃₆P₂

CAS Number:

528565-79-9

Molecular Weight:

506.60

NACRES:

NA.22

PubChem Substance ID:

24884944

UNSPSC Code:

12352005

MDL number:

MFCD07369027

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Properties

form

solid

Quality Segment

100

mp

143-147 °C

functional group

phenyl, phosphine

SMILES string

C1C[C@@H](P(CCP2[C@H](CC[C@@H]2c3ccccc3)c4ccccc4)[C@H]1c5ccccc5)c6ccccc6

InChI

1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m1/s1

InChI key

VHHAZLMVLLIMHT-YFRBGRBWSA-N

Description

Application

(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane can be used:

As a chiral ligand in the 1,3-dipolar cycloaddition reaction of azomethyne yielded [70]fullerene enantiomers; catalyzed by silver.
As a component of the catalytic system along with silver, which is used for the synthesis of fullerene hybrids.

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Legal Information

Sold in collaboration with Namena Corp. for research purposes only.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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