667854
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane
kanata purity
Synonym(s):
(S,S)-Ph-BPE,BPE
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About This Item
Empirical Formula (Hill Notation):
C34H36P2
CAS Number:
Molecular Weight:
506.60
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI key
VHHAZLMVLLIMHT-CUPIEXAXSA-N
SMILES string
C1C[C@H](P(CCP2[C@@H](CC[C@H]2c3ccccc3)c4ccccc4)[C@@H]1c5ccccc5)c6ccccc6
InChI
1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m0/s1
form
solid
mp
143-147 °C
functional group
phenyl, phosphine
Quality Level
Related Categories
General description
Chiral Phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides
Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study
Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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