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667854

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane

Name: (+)-1,2-Bis((2<I>S</I>,5<I>S</I>)-2,5-diphenylphospholano)ethane
Brand: ALDRICH

kanata purity

Synonym(s):

(S,S)-Ph-BPE,BPE

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About This Item

Empirical Formula (Hill Notation):

C₃₄H₃₆P₂

CAS Number:

824395-67-7

Molecular Weight:

506.60

NACRES:

NA.22

PubChem Substance ID:

24884945

UNSPSC Code:

12352005

MDL number:

MFCD07369028

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Properties

Quality Segment

100

form

solid

mp

143-147 °C

functional group

phenyl, phosphine

SMILES string

C1C[C@H](P(CCP2[C@@H](CC[C@H]2c3ccccc3)c4ccccc4)[C@@H]1c5ccccc5)c6ccccc6

InChI

1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m0/s1

InChI key

VHHAZLMVLLIMHT-CUPIEXAXSA-N

Description

General description

Chiral Phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides

Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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