Silver bis(trifluoromethanesulfonyl)imide

Name: Silver bis(trifluoromethanesulfonyl)imide
Brand: ALDRICH

97%, solid

Synonym(s):

Silver bis(trifluoromethanesulfonyl)amide, Silver bis(trifluoromethylsulfonyl)amide, Silver triflimide

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About This Item

Empirical Formula (Hill Notation):

C₂AgF₆NO₄S₂

CAS Number:

189114-61-2

Molecular Weight:

388.01

UNSPSC Code:

12161600

PubChem Substance ID:

24884953

NACRES:

NA.22

MDL number:

MFCD08457644

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Properties

Product Name

Silver bis(trifluoromethanesulfonyl)imide, 97%

Quality Level

100

assay

97%

form

solid

reaction suitability

core: silver, reagent type: catalyst

mp

248.8 °C

SMILES string

FC(F)(F)S(=O)(=O)N([Ag])S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Ag/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key

HSYLTRBDKXZSGS-UHFFFAOYSA-N

Description

General description

Silver bis(trifluoromethanesulfonyl)imide is a silver-based salt that is widely used as a catalyst in organic synthesis. It is used in the C₃ regioselective alkylation of indole derivatives via conjugated addition type reactions with α, β-enones. It is also used as a p-type dopant for efficient and stable solid-state dye-sensitized and perovskite solar cells.