Key Documents

668281

1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

Name: 1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-&#956;-hydrotetracarbonyldiruthenium(II)
Brand: ALDRICH

98%, solid

Synonym(s):

2,4-Cyclopentadien-1-one, 2,3,4,5-tetraphenyl-, ruthenium complex, Shvo’s Catalyst, Tetracarbonyl-μ-hydro[(1,2,3,4,5-H)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-H)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]diruthenium

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About This Item

Empirical Formula (Hill Notation):

C₆₂H₄₂O₆Ru₂

CAS Number:

104439-77-2

Molecular Weight:

1085.13

MDL number:

MFCD03840556

UNSPSC Code:

12161600

PubChem Substance ID:

24884974

NACRES:

NA.22

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Properties

Product Name

1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II), 98%

Quality Level

100

assay

98%

form

solid

reaction suitability

core: ruthenium, reagent type: catalyst

mp

223-227 °C

SMILES string

[Ru][RuH].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O[C]1[C]([C]([C]([C]1c2ccccc2)c3ccccc3)c4ccccc4)c5ccccc5.O=C6C(c7ccccc7)=C(c8ccccc8)C(c9ccccc9)=C6c%10ccccc%10

InChI

1S/C29H21O.C29H20O.4CO.2Ru.H/c2*30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;4*1-2;;;/h1-20,30H;1-20H;;;;;;;

InChI key

PISMVXYUJBWZFB-UHFFFAOYSA-N

Description

Application

Has found numerous applications as a versatile catalyst in organic synthesis, including the reduction of aldehydes and ketones to alcohols, bimolecular disproportionation reaction of aldehydes to esters, isomerization of allylic alcohols and oxidation of alcohols.

Shvo′s Catalyst

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Articles

Shvo’s Catalyst

Efficient epimerization catalyst for enzyme mediated dynamic kinetic resolution (DKR).

Combination of enzymes and metal catalysts. A powerful approach in asymmetric catalysis.

Oscar Pàmies et al.

Chemical reviews, 103(8), 3247-3262 (2003-08-14)

Prabhakaran, R.

Synlett, 2048-2048 (2004)

Global Trade Item Number

SKU	GTIN
668281-100MG	04061833549285
668281-500MG	04061833549292