669083
2,2,2-Trifluoroethyl formate
95%
Synonym(s):
TFEF
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About This Item
Linear Formula:
CF3CH2OC(O)H
CAS Number:
Molecular Weight:
128.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Product Name
2,2,2-Trifluoroethyl formate, 95%
InChI
1S/C3H3F3O2/c4-3(5,6)1-8-2-7/h2H,1H2
SMILES string
[H]C(=O)OCC(F)(F)F
InChI key
CAFROQYMUICGNO-UHFFFAOYSA-N
assay
95%
refractive index
n20/D <1.001
density
1.317 g/mL at 25 °C
functional group
fluoro
Quality Level
Related Categories
Application
Reagent for the formylation of alcohols and amines. Hydroxylamines provide high yields of the N-formylated product.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
45.0 °F - closed cup
flash_point_c
7.2 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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David R Hill et al.
Organic letters, 4(1), 111-113 (2002-01-05)
[reaction: see text] Treatment of a variety of alcohols, amines, and N-hydroxylamines with 2,2,2-trifluoroethyl formate gave the corresponding formylated adducts in high yields.
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