669156
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
solid
Synonym(s):
Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium
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About This Item
Product Name
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II),
SMILES string
Cl[Ru].[C-]#[O+].[C-]#[O+].c1ccc(cc1)[C]2[C]([C]([C]([C]2c3ccccc3)c4ccccc4)c5ccccc5)c6ccccc6
InChI
1S/C35H25.2CO.ClH.Ru/c1-6-16-26(17-7-1)31-32(27-18-8-2-9-19-27)34(29-22-12-4-13-23-29)35(30-24-14-5-15-25-30)33(31)28-20-10-3-11-21-28;2*1-2;;/h1-25H;;;1H;/q;;;;+1/p-1
InChI key
NGSBLRJKXUHTOC-UHFFFAOYSA-M
form
solid
reaction suitability
core: ruthenium, reagent type: catalyst
mp
152-167 °C
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Application
- Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
- Ligand exchange
- Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds
Catalyst for:
- (S)-Selective dynamic kinetic resolution of secondary alcohols
- Stereoselective synthesis of neonicorinoide pesticide derivatives
- Divergent asymmetric synthesis of 3,5-disubstituted piperidines
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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