670693
(−)-2,3-Bis[(2R,5R)-2,5-dimethylphospholano]maleic anhydride
98%
Synonym(s):
3,4-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]furan-2,5-dione, catASium® M(R)
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About This Item
Empirical Formula (Hill Notation):
C16H24O3P2
CAS Number:
Molecular Weight:
326.31
PubChem Substance ID:
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
9428339
MDL number:
SMILES string
C[C@@H]1CC[C@@H](C)P1C2=C(P3[C@H](C)CC[C@H]3C)C(=O)OC2=O
InChI
1S/C16H24O3P2/c1-9-5-6-10(2)20(9)13-14(16(18)19-15(13)17)21-11(3)7-8-12(21)4/h9-12H,5-8H2,1-4H3/t9-,10-,11-,12-/m1/s1
InChI key
OQHMFJKKVZGWDC-DDHJBXDOSA-N
assay
≥98% (31P-NMR), 98%
Quality Level
Related Categories
General description
Sold in collaboration with Solvias AG
Application
(−)-2,3-Bis[(2R,5R)-2,5-dimethylphospholano]maleic anhydride can be used to prepare its rhodium metal complexes, which are used as catalysts in the asymmetric hydrogenation reactions of alkenes.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Legal Information
catASium is a registered trademark of Umicore AG & Co. KG
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Activation, Deactivation and Reversibility Phenomena in Homogeneous Catalysis: A Showcase Based on the Chemistry of Rhodium/Phosphine Catalysts
Alberico E, et al.
Catalysts, 9(7), 582-582 (2019)
Asymmetric Synthesis of Potential Precursors of the HIV Drug MC1220 and Its Analogues by Hydrogenation of (1-Arylvinyl) pyrimidines
Loksha YM and Pedersen EB
Journal of Heterocyclic Chemistry, 55(6), 1352-1357 (2018)
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