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Merck
CN

673307

Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate

greener alternative

solid

Synonym(s):

(Cyclopentadienyltris(acetonitrile)ruthenium hexafluorophosphate, Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate

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About This Item

Linear Formula:
[(C5H5)Ru(CH3CN)3]PF6
CAS Number:
Molecular Weight:
434.28
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate,

form

solid

Quality Level

reaction suitability

core: ruthenium, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

storage temp.

2-8°C

SMILES string

[Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F

InChI

1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;3*1-2-3;1-7(2,3,4,5)6;/h1-5H;3*1H3;;/q;;;;-1;+1

InChI key

HJQVFVSAQOQXRG-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Catalyst for:
  • Regioselective and stereoselective dehydrative allylation of nucleophiles
  • O-H Insertion and condensation reactions
  • Hydrosilylation
  • Decarboxylative allylic etherification
  • Claisen rearrangement of unactivated allyl vinyl ethers


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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The Herzon group has developed highly active catalysts for the anti-Markovnikov hydration and reductive hydration of terminal alkynes to form aldehydes and linear alcohols, respectively.


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A series of side-chain functionalized polytetrahydrofuran (PTHF) derivatives were synthesized via the blue-light photocatalytic thiol-ene "click" reaction. Firstly, unsaturated polytetrahydrofuran (UPTHF) as a new unsaturated polyether was synthesized via condensation polymerization of cis-2-butene-1,4-diol and trans-1,4-dibromo-2-butene using potassium hydroxide (KOH) as



Global Trade Item Number

SKUGTIN
P-905-1ML04061834261735
673307-250MG04061833483718
673307-1G04061826724576