673986
2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine
≥94%
Synonym(s):
(3aR,3′aR,8aS,8′aS)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole, (3aR,8aS)-in-pybox
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About This Item
Empirical Formula (Hill Notation):
C25H19N3O2
CAS Number:
Molecular Weight:
393.44
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Quality Segment
assay
≥94%
form
solid
optical activity
[α]20/D +386°, c = 1 in methylene chloride(lit.)
mp
284 °C (dec.)
functional group
ether
SMILES string
C1[C@@H]2OC(=N[C@@H]2c3ccccc13)c4cccc(n4)C5=N[C@H]6[C@H](Cc7ccccc67)O5
InChI
1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m0/s1
InChI key
BZSJUFJXCHHRHW-MYDTUXCISA-N
Application
Catalytic ligand used for:
- [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
- Enantioselective Mukaiyama-aldol reactions
- Enantioselective carbonyl-ene reactions
- Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
- Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
- Enantioselective Diels-Alder reaction
- Ni-catalyzed cross-coupling reactions
hcodes
Hazard Classifications
Aquatic Chronic 4
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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