673986
2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine
≥94%
Synonym(s):
(3aR,3′aR,8aS,8′aS)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole, (3aR,8aS)-in-pybox
Select a Size
About This Item
Product Name
2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, ≥94%
InChI
1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m0/s1
SMILES string
C1[C@@H]2OC(=N[C@@H]2c3ccccc13)c4cccc(n4)C5=N[C@H]6[C@H](Cc7ccccc67)O5
InChI key
BZSJUFJXCHHRHW-MYDTUXCISA-N
assay
≥94%
form
solid
optical activity
[α]20/D +386°, c = 1 in methylene chloride(lit.)
mp
284 °C (dec.)
functional group
ether
Quality Level
Related Categories
Application
- [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
- Enantioselective Mukaiyama-aldol reactions
- Enantioselective carbonyl-ene reactions
- Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
- Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
- Enantioselective Diels-Alder reaction
- Ni-catalyzed cross-coupling reactions
hcodes
Hazard Classifications
Aquatic Chronic 4
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Articles
The PYBOX ligand, consisting of a pyridine ring flanked by two oxazoline groups, was introduced in 1989 by Nishiyama.
PYBOX配体由吡啶环侧接两个恶唑啉基团组成，由Nishiyama在1989年合成成功。
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service