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674133

Palladium nanoparticles entrapped in aluminum hydroxide matrix

0.5 wt. % loading, solid

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About This Item

Linear Formula:
Pd/AlO(OH)
UNSPSC Code:
12161600
PubChem Substance ID:
24885199
NACRES:
NA.22
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Product Name

Palladium nanoparticles entrapped in aluminum hydroxide matrix, 0.5 wt. % loading

form

solid

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

SMILES string

[Pd].O[Al]=O

InChI

1S/Al.H2O.O.Pd/h;1H2;;/q+1;;;/p-1

InChI key

BBEPUHUDSUQPRM-UHFFFAOYSA-M

General description

A robust palladium heterogenous catalyst.

Application

A recyclable nanocatalyst for the racemization of primary amines. When used in conjunction with a lipase produces enantiopure amines by Dynamic Kinetic Resolution.
Catalyst for:
  • Solvent-free hydrogenation
  • Aerobic alcohol oxidation

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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