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Merck
CN

674192

Trioxo(triphenylsilyloxy)rhenium(VII)

solid

Sustainability features

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About This Item

Empirical Formula (Hill Notation):
C18H15O4ReSi
CAS Number:
Molecular Weight:
509.60
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Trioxo(triphenylsilyloxy)rhenium(VII),

form

solid

Quality Segment

reaction suitability

core: rhenium, reagent type: catalyst

sustainability

Sustainability features

mp

108-110 °C

greener alternative category

storage temp.

2-8°C

SMILES string

O=[Re](=O)(=O)O[Si](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H15OSi.3O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;/h1-15H;;;;/q-1;;;;+1

InChI key

JFZHOPFMMQQPJF-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This high-oxidation state rhenium catalyst is used for selective oxidations, including epoxidation of olefins, alcohol oxidation, and other oxygen-transfer reactions. Its unique metal center delivers excellent selectivity and high catalytic activity under mild conditions, aligning with Green Chemistry principle "Catalysis". Click here for more information.

Application

Catalyst for:
  • Cycloisomerization reactions
  • Prins dimerization
  • Prins cyclization reactions


Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



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