677191
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether
96%
Synonym(s):
(2R)-2-[Diphenyl[(trimethylsilyl)oxy]methyl]pyrrolidine, (R)-α,α-Diphenylprolinol trimethylsilyl ether
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About This Item
Empirical Formula (Hill Notation):
C20H27NOSi
CAS Number:
Molecular Weight:
325.52
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Quality Segment
assay
96%
form
solid
optical activity
[α]22/D +52±5°, c = 1 in chloroform
reaction suitability
reagent type: organic catalyst
refractive index
n
density
1.0459 g/mL at 25 °C
functional group
phenyl
storage temp.
2-8°C
SMILES string
C[Si](C)(C)OC([C@H]1CCCN1)(c2ccccc2)c3ccccc3
InChI
1S/C20H27NOSi/c1-23(2,3)22-20(19-15-10-16-21-19,17-11-6-4-7-12-17)18-13-8-5-9-14-18/h4-9,11-14,19,21H,10,15-16H2,1-3H3/t19-/m1/s1
InChI key
RSUHWMSTWSSNOW-LJQANCHMSA-N
General description
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether is a diarylprolinol silyl ether organocatalyst.
Application
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether can be used as a catalyst to synthesize:
- Glycofused tricyclic derivatives, which are used in the development of amyloid β-peptide diagnostic tools.
- Cyclohexene carbaldehyde derivatives by reacting benzoylnitromethane with aliphatic enals.
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
dust mask type N95 (US), Eyeshields, Gloves
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