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677892

Tetrakis(acetonitrile)copper(I) tetrafluoroborate

greener alternative

97%, solid

Synonym(s):

Cu(MeCN)4BF4, Copper(I) tetra(acetonitrile) tetrafluoroborate, Tetra(acetonitrile)copper(1+) tetrafluoroborate

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About This Item

Empirical Formula (Hill Notation):
C8H12BCuF4N4
CAS Number:
15418-29-8
Molecular Weight:
314.56
UNSPSC Code:
12161600
PubChem Substance ID:
24885403
NACRES:
NA.22
MDL number:
MFCD09265110
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Product Name

Tetrakis(acetonitrile)copper(I) tetrafluoroborate, 97%

Quality Level

100

assay

97%

form

solid

reaction suitability

core: copper, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

Aligned,

SMILES string

[Cu+].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F

InChI

1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1

InChI key

YZGSKMIIVMCEFE-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for greener oxidation of alcohols under aerobic conditions.

Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000501979
0000501979
0000501036
0000501035
0000501035

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Moore, J. A.; Partain, E. M.
The Journal of Organic Chemistry, 48, 1105-1105 (1983)
Tobias Schneider et al.
Scientific reports, 9(1), 19991-19991 (2019-12-29)
Ubiquitylation is an eminent posttranslational modification referring to the covalent attachment of single ubiquitin molecules or polyubiquitin chains to a target protein dictating the fate of such labeled polypeptide chains. Here, we have biochemically produced artificially Lys11-, and Lys27-, and
Bethell, D.; Jenkins, I. L.; Quan, P. M.
J. Chem. Soc. Perkin Trans. II, 1789-1789 (1985)
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Global Trade Item Number

SKUGTIN
677892-5G04061832748474
677892-1G04061832748467