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677922

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct

solid

Synonym(s):

[Bis(trifluoromethanesulfonyl)imidate](PPh3)gold(I) (2:1) toluene adduct

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About This Item

Linear Formula:
(C20H15AuF6NO4PS2) 2 · C7H8
Molecular Weight:
1570.93
UNSPSC Code:
12161600
PubChem Substance ID:
24885406
NACRES:
NA.22
MDL number:
MFCD09038445
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Product Name

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct,

form

solid

Quality Segment

100

reaction suitability

core: gold, reagent type: catalyst

SMILES string

[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.CC1=CC=CC=C1.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/2C18H15P.C7H8.2C2F6NO4S2.2Au/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;;/h2*1-15H;2-6H,1H3;;;;/q;;;2*-1;2*+1

InChI key

SIVCTOVPPFSWEF-UHFFFAOYSA-N

Application

Gold Catalysts — 21st Century ′Gold Rush′
[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct can be used as a catalyst in the 1,3-isomerisation of propargylic alcohols to enones via Meyer-Schuster rearrangement.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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