680990
1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene
Synonym(s):
R,R-Et-Ferrocelane™
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Empirical Formula (Hill Notation):
C26H40FeP2
CAS Number:
Molecular Weight:
470.39
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
form
solid
Quality Segment
optical activity
[α]20/D +380°, c = 1 in chloroform
mp
85-91 °C
functional group
phosphine
SMILES string
C[Fe]C.CC[C@@H]1CC[C@@H](CC)P1[C@@H]2CCCC2.CC[C@@H]3CC[C@@H](CC)P3[C@H]4CCCC4
InChI
1S/2C13H25P.2CH3.Fe/c2*1-3-11-9-10-12(4-2)14(11)13-7-5-6-8-13;;;/h2*11-13H,3-10H2,1-2H3;2*1H3;/t2*11-,12-;;;/m11.../s1
InChI key
CPUKIDAUDCWIRT-QULUYMGFSA-N
Application
1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene can be used:
- As a catalyst in the asymmetric hydrogenation reactions of olefins and ketones.
- As a component of a rhodium based precatalyst, applicable in the 2-methylenesuccinamic acid hydrogenation reaction.
Legal Information
Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.
Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.