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Merck
CN

682098

Borane-ammonia complex

greener alternative

95%

Synonym(s):

Amminetrihydroboron, Borazane

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About This Item

Linear Formula:
H3N · BH3
CAS Number:
Molecular Weight:
30.87
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
Assay:
95%
Form:
solid
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Quality Level

assay

95%

form

solid

greener alternative product characteristics

Design for Energy Efficiency
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Greener Alternative Product

greener alternative category

SMILES string

B.N

InChI

1S/BH3.H3N/h2*1H3

InChI key

WZMUUWMLOCZETI-UHFFFAOYSA-N

General description

Ammonia borane also known as borazane has high hydrogen content (about 20% mass). Thermal decomposition of borazane take place in the temperature range 350-410K accompanied by hydrogen release and heat evolution. It may find use as a hydrogen source in fuel cells in the future.
Borane-ammonia complex is a novel material, where ammonia is tightly bound to a ligand through all four of its atoms. It is a donor-acceptor complex that is formed by electron donated by a Lewis base (NH3) to a Lewis acid (BH3). It shows a B-N bond distance of 1.564 Å.
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Application

Borazane is popularly used as an ammonia borane (AB) source for the formation of hexagonal boron nitride monolayers which are used as a substrate for graphene growth.


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves



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Qiuxia Zhou et al.
Journal of colloid and interface science, 508, 542-550 (2017-09-05)
The design and fabrication of highly active and durable catalysts for the ammonia borane (AB) hydrolysis has been one of significant issues in the application of green and economic hydrogen energy. Nanoporous (NP) PtCo/Co
Hyo Ju Park et al.
Science advances, 6(10), eaay4958-eaay4958 (2020-03-18)
Hexagonal boron nitride (hBN) is an insulating two-dimensional (2D) material with a large bandgap. Although known for its interfacing with other 2D materials and structural similarities to graphene, the potential use of hBN in 2D electronics is limited by its
Wei Fu et al.
ACS nano, 14(4), 3917-3926 (2020-02-13)
The breaking of multiple symmetries by periodic lattice distortion at a commensurate charge density wave (CDW) state is expected to give rise to intriguing interesting properties. However, accessing the commensurate CDW state on bulk TaS2 crystals typically requires cryogenic temperatures



Global Trade Item Number

SKUGTIN
682098-100G04061833607213
682098-10G04061832754901
682098-1G04061832754918
682098-500G04061835571772