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Merck
CN

682098

Borane-ammonia complex

95%

Sustainability features

Synonym(s):

Amminetrihydroboron, Borazane

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About This Item

Linear Formula:
H3N · BH3
CAS Number:
Molecular Weight:
30.87
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
Assay:
95%
Form:
solid
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Quality Segment

assay

95%

form

solid

sustainability

Sustainability features

application(s)

hydrogen and fuel cell

greener alternative category

SMILES string

B.N

InChI

1S/BH3.H3N/h2*1H3

InChI key

WZMUUWMLOCZETI-UHFFFAOYSA-N

General description

Ammonia borane also known as borazane has high hydrogen content (about 20% mass). Thermal decomposition of borazane take place in the temperature range 350-410K accompanied by hydrogen release and heat evolution. It may find use as a hydrogen source in fuel cells in the future.
Borane-ammonia complex is a novel material, where ammonia is tightly bound to a ligand through all four of its atoms. It is a donor-acceptor complex that is formed by electron donated by a Lewis base (NH3) to a Lewis acid (BH3). It shows a B-N bond distance of 1.564 Å.
This product aligns with one or more of the 12 Principles of Green Chemistry Find details here.

Application

Borazane is popularly used as an ammonia borane (AB) source for the formation of hexagonal boron nitride monolayers which are used as a substrate for graphene growth.


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Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves



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