682314
(S)-N-Methyl-N-diphenylphosphino-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine
Synonym(s):
(1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, Methyl-BoPhoz
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About This Item
Empirical Formula (Hill Notation):
C37H35FeNP2
CAS Number:
Molecular Weight:
611.47
UNSPSC Code:
12352005
PubChem Substance ID:
MDL number:
form
solid
mp
104.1-109.2 °C
functional group
amine, phosphine
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
InChI
1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
InChI key
ZIAZHUWEJYUGEO-FBHGDYMESA-N
Application
Methyl-BoPhoz can be used:
- As an efficient ligand for asymmetric hydrogenation reactions.
- To synthesize a single enantiomer of cyclopropylalanine via hydrogenation reaction using rhodium catalyst.
- To prepare chiral phenylalanine derivatives from α-amido cinnamic acids (or esters) using rhodium catalyst.
Legal Information
Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6590115 and any patents arising therefrom apply.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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