Key Documents

682942

1,1′-Bis[(11bS)-dinaphtho[2,1-d:1′, 2′-f][1,3,2]dioxaphosphepin-4-yl]ferrocene

Name: 1,1′-Bis[(11b<I>S</I>)-dinaphtho[2,1-<I>d</I>:1′, 2′-f][1,3,2]dioxaphosphepin-4-yl]ferrocene
Brand: ALDRICH

Synonym(s):

S,S-Reetz F-Diphosphonite

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About This Item

Empirical Formula (Hill Notation):

C₅₀H₃₂FeO₄P₂

CAS Number:

260395-56-0

Molecular Weight:

814.58

UNSPSC Code:

12352000

PubChem Substance ID:

329760783

MDL number:

MFCD10566988

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Properties

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56.[CH]7[CH][CH][C]([CH]7)P8Oc9ccc%10ccccc%10c9-c%11c(O8)ccc%12ccccc%11%12

InChI

1S/2C25H16O2P.Fe/c2*1-5-11-20-17(7-1)13-15-22-24(20)25-21-12-6-2-8-18(21)14-16-23(25)27-28(26-22)19-9-3-4-10-19;/h2*1-16H;

InChI key

WMKZSCONNPWJGW-UHFFFAOYSA-N

Description

Application

Used in a variety of asymmetric reactions, including: hydrogenations and conjugate additions.

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number

12806LH

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Reetz, M. T.

Pure and Applied Chemistry. Chimie Pure Et Appliquee, 71, 1503-1503 (1999)

Reetz, M. T. et al.

Chemical Communications (Cambridge, England), 2077-2077 (1998)