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683108

Chiralyst P310

99%, Umicore, solid

Synonym(s):

(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I), Acetylacetonato(1,5-cyclooctadiene)rhodium(I), Rh(acac)(COD)

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About This Item

Empirical Formula (Hill Notation):
C13H19O2Rh
CAS Number:
12245-39-5
Molecular Weight:
310.19
UNSPSC Code:
12161600
PubChem Substance ID:
329760794
NACRES:
NA.22
MDL number:
MFCD00075046
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Product Name

Chiralyst P310, Umicore, 99%

Quality Level

100

assay

99%

form

solid

reaction suitability

core: rhodium, reaction type: Cross Couplings, reagent type: catalyst

mp

138-140 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Rh].C1CC=CCCC=C1

InChI

1S/C8H12.C5H8O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;

InChI key

TVGPAHONTUMCNP-DWVXZKBMSA-M

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Catalyst/precursor for enantioselective/asymmetric hydrogenations, isomerization/hydroformylations, carbozincation reactions, and silylation of aryl electrophiles

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ7685
MKCN7844
MKCL9312
MKCC7036
MKCC0552

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Articles

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

New Phosphorus Ligands for the Rhodium-Catalyzed Isomerization/Hydroformylation of Internal Octenes.
Detlef Selent et al.
Angewandte Chemie (International ed. in English), 40(9), 1696-1698 (2001-05-16)
Yonehara, K.; Hashizume, T. et al.
The Journal of Organic Chemistry, 64, 5598-5598 (1999)
Benoit Gourdet et al.
Journal of the American Chemical Society, 131(11), 3802-3803 (2009-03-04)
A new rhodium-catalyzed carbozincation of ynamides has been developed, using diorganozinc reagents or functionalized alkylzinc halides. The reactions are highly regio- and stereoselective, allowing access to a wide range of multisubstituted enamides, which are increasingly important building blocks for organic
View All Related Papers

Global Trade Item Number

SKUGTIN
683108-2G04061833550090
683108-500MG04061833474198