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683159

Chiralyst P468

Name: Chiralyst P468
Brand: ALDRICH

Umicore, powder

Synonym(s):

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, Bis(1,5-cyclooctadiene)rhodium triflate

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About This Item

Empirical Formula (Hill Notation):

C₁₇H₂₄F₃O₃RhS

CAS Number:

99326-34-8

Molecular Weight:

468.34

UNSPSC Code:

12161600

PubChem Substance ID:

329760799

NACRES:

NA.22

MDL number:

MFCD00143752

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Properties

Product Name

Chiralyst P468, Umicore

Quality Segment

100

form

powder

reaction suitability

core: rhodium, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

159 °C (dec. literature value) (lit.), 83-97 °C (dec. experimental value)

greener alternative category

Aligned

SMILES string

[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b2*2-1-,8-7-;;

InChI key

GOPBTCMAUMSOBX-QMDOQEJBSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a versatile precatalyst for homogeneous catalysis, with demonstrated activity in targeted reactions. Click here for more information.

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

pictograms

GHS07

signalword

Warning

hcodes

H319

pcodes

P264 - P280 - P305 + P351 + P338 - P337 + P313

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c