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687510

Chloro[2-dicyclohexyl(2′,4′,6′-trisopropylbiphenyl)phosphine]gold(I)

greener alternative

solid

Synonym(s):

2-Dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl gold(I) chloride, XPhos AuCl

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About This Item

Empirical Formula (Hill Notation):
C33H49AuClP
CAS Number:
854045-94-6
Molecular Weight:
709.14
UNSPSC Code:
12161600
PubChem Substance ID:
329761134
NACRES:
NA.22
MDL number:
MFCD09842765
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Product Name

Chloro[2-dicyclohexyl(2′,4′,6′-trisopropylbiphenyl)phosphine]gold(I),

form

solid

Quality Level

100

reaction suitability

core: gold, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

243-250 °C

greener alternative category

Aligned

SMILES string

Cl[Au].CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2ccccc2P(C3CCCCC3)C4CCCCC4

InChI

1S/C33H49P.Au.ClH/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;;1H/q;+1;/p-1

InChI key

AFVLNRJUCUDBHP-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Gold Catalysts — 21st Century ′Gold Rush′
Catalyst for:
  • Michael addition and intramolecular hydroalkylation reactions
  • Cascade cyclization of diynes
  • Hydroarylation of allenes via a highly regioselective carbon-carbon bond formation producing six-membered rings
  • Alkyne cyclizations in a Holey catalytic environment

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
SHBM9185
SHBB8141V
10625EH
10525EH

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Articles

Gold Catalyst Applications

Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.

Global Trade Item Number

SKUGTIN
687510-250MG04061832764498
687510-1G04061826706794