688320
(S)-VAPOL hydrogenphosphate
Synonym(s):
(S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3′,4′-f][1,3,2]dioxaphosphepin-18-oxide, (S)-2,2′-Diphenyl-3,3′-biphenanthryl-4,4′-diyl phosphate, (S)-VAPOL phosphoric acid
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About This Item
SMILES string
[P]1(=O)(Oc2c3c4c(ccc3cc(c2c6c(c7c8c(ccc7cc6c9ccccc9)cccc8)O1)c5ccccc5)cccc4)O
InChI
1S/C40H25O4P/c41-45(42)43-39-35-29(21-19-27-15-7-9-17-31(27)35)23-33(25-11-3-1-4-12-25)37(39)38-34(26-13-5-2-6-14-26)24-30-22-20-28-16-8-10-18-32(28)36(30)40(38)44-45/h1-24H,(H,41,42)
InChI key
YKIJNEDTUDPMNC-UHFFFAOYSA-N
form
solid
optical activity
[α]22/D +412°, c = 1 in chloroform
mp
>400 °C
functional group
phenyl, phosphate
Quality Level
Related Categories
Application
- Benzoyloxylation of (aryl)oxindoles with benzoyl peroxide
- Enantioselective synthesis of homoaldols and cyclic acetals via kinetic resoln of homoaldols
- Desymmetrization of mono- and bicyclic N-acyl meso-aziridines by ring opening
- Highly enantioselective addition of imides to imines to give aminals
- Friedel-Crafts reaction of pyrroles with benzylidenebenzamides
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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