688320
(S)-VAPOL hydrogenphosphate
Synonym(s):
(S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3′,4′-f][1,3,2]dioxaphosphepin-18-oxide, (S)-2,2′-Diphenyl-3,3′-biphenanthryl-4,4′-diyl phosphate, (S)-VAPOL phosphoric acid
Select a Size
About This Item
form
solid
Quality Level
optical activity
[α]22/D +412°, c = 1 in chloroform
mp
>400 °C
functional group
phenyl, phosphate
SMILES string
[P]1(=O)(Oc2c3c4c(ccc3cc(c2c6c(c7c8c(ccc7cc6c9ccccc9)cccc8)O1)c5ccccc5)cccc4)O
InChI
1S/C40H25O4P/c41-45(42)43-39-35-29(21-19-27-15-7-9-17-31(27)35)23-33(25-11-3-1-4-12-25)37(39)38-34(26-13-5-2-6-14-26)24-30-22-20-28-16-8-10-18-32(28)36(30)40(38)44-45/h1-24H,(H,41,42)
InChI key
YKIJNEDTUDPMNC-UHFFFAOYSA-N
Application
- Benzoyloxylation of (aryl)oxindoles with benzoyl peroxide
- Enantioselective synthesis of homoaldols and cyclic acetals via kinetic resoln of homoaldols
- Desymmetrization of mono- and bicyclic N-acyl meso-aziridines by ring opening
- Highly enantioselective addition of imides to imines to give aminals
- Friedel-Crafts reaction of pyrroles with benzylidenebenzamides
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Articles
TRIP and TiPSY Chiral Phosphoric Acid Catalysts
TRIP和TiPSY手性磷酸催化剂
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 688320-100MG | 04061833550496 |
| 688320-500MG | 04061833474259 |