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Merck
CN

688738

Basolite® A100

greener alternative

produced by BASF

Synonym(s):

Aluminum terephthalate, MIL-53(Al)

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About This Item

Empirical Formula (Hill Notation):
C8H5AlO5
Molecular Weight:
208.10
NACRES:
NA.23
UNSPSC Code:
26111700
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Quality Level

form

tablet

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

1100-1500 m2/g

particle size distribution

31.55 μm (D50)

bulk density

0.4 g/cm3

greener alternative category

General description

Basolite®A100 is a microporous metal-organic framework (MOF), which consists of three-dimensional networks with micropores up to 900 pm in diameter. It has characteristics that are identical to MIL-53(Al) as it contains octahedral AlO4(OH)2 units connected through 1,4-benzenedicarboxylate ligands. It allows the formation of a framework with a high specific surface of 1084 m2g-1 area and a pore volume of about 0.51 cm2g-1.
Basolite (TM) A100 is also known as MIL-53(Al). It is an ultramicroporous metal framework (MOF).
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Basolite®A100 is majorly used in the binary gas separation of CO2/CH4 and CO2/N2. It can also be used for gas adsorption (hydrogen gas) and for the supercritical adsorption of CO2.
Basolite (TM) A100 was used in the separation of C8-alkylaromatic compounds.

Other Notes

can be reactivated at 200°C (vacuum)

Legal Information

Basolite is a registered trademark of BASF SE


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Danger

Hazard Classifications

Eye Irrit. 2 - Repr. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges



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Articles

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

金属有机骨架(MOF)是一类相对较新的多孔晶体材料,具有广泛的应用范围。MOF由充当接合处的金属离子或簇组成,并由多向有机配体所结合,而其在网络结构中作为接头。


A combined computational and experimental study of high pressure and supercritical CO2 adsorption on Basolite MOFs
Deniz E, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 175(1), 34-42 (2013)
MOF-containing mixed-matrix membranes for CO2/CH4 and CO2/N2 binary gas mixture separations
Basu S, et al.
Separation and Purification Technology, 81(1), 31-40 (2011)
A complete procedure for acidic gas separation by adsorption on MIL-53 (Al)
Heymans N, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 154(1), 93-99 (2012)



Global Trade Item Number

SKUGTIN
688738-500G04061833600153
688738-10G04061833381052
688738-100G04061833466681