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690872

Basolite® F300

greener alternative

produced by BASF

Synonym(s):

Fe-BTC, Iron 1,3,5-benzenetricarboxylate

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About This Item

Empirical Formula (Hill Notation):
C9H3FeO6
CAS Number:
1195763-37-1
Molecular Weight:
262.96
NACRES:
NA.23
PubChem Substance ID:
329761369
UNSPSC Code:
26111700
MDL number:
MFCD11656051
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Quality Level

100

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

120-190 m2/g

bulk density

0.16‑0.35 g/cm3

greener alternative category

, Enabling

SMILES string

O=C1O[Fe]2OC(=O)c3cc1cc(c3)C(=O)O2

InChI

1S/C9H6O6.Fe/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;/h1-3H,(H,10,11)(H,12,13)(H,14,15);/q;+3/p-3

InChI key

UTYFBNKMZYRAFO-UHFFFAOYSA-K

General description

Basolite®F300 (Fe-BTC) is a porous metal organic framework (MOF) that is used as a highly active catalyst for Lewis acid reactions such as acetalization of aldehydes and aldol condensation. It has a hybrid supertetrahedral build up from oxocentered trimmers of iron(III) octahedron that are connected by trimesate anions.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Fe-BTC based MOF can be used in greener applications such as energy storage through lithium ion batteries. It can also be used in the supercritical adsorption of CO2.

Legal Information

Basolite is a registered trademark of BASF SE

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 2

target_organs

Eyes,Central nervous system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBJ5843
STBD9968V
S61151V
S61151
S58688

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Articles

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

金属有机框架MOF_光伏和太阳能电池-默克生命科学

金属有机骨架（MOF）是一类相对较新的多孔晶体材料，具有广泛的应用范围。MOF由充当接合处的金属离子或簇组成，并由多向有机配体所结合，而其在网络结构中作为接头。

Comparison of porous iron trimesates basolite F300 and MIL-100 (Fe) as heterogeneous catalysts for lewis acid and oxidation reactions: roles of structural defects and stability
Dhakshinamoorthy A, et al.
ACS Catalysis, 2(10), 2060-2065 (2012)
Facile synthesis of the Basolite F300-like nanoscale Fe-BTC framework and its lithium storage properties
Hu X, et al.
Royal Society of Chemistry Advances, 6(115), 114483-114490 (2016)
A combined computational and experimental study of high pressure and supercritical CO2 adsorption on Basolite MOFs
Deniz E, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 175(115), 34-42 (2013)
View All Related Papers

Global Trade Item Number

SKUGTIN
690872-10G04061832765204
690872-500G04061833499849
690872-100G04061833314906