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Merck
CN

691496

Borane di(tert-butyl)phosphine complex

97%

Synonym(s):

(Di-tert-butylphosphine)trihydroboron, Di-tert-butylphosphine compound with borane (1:1), Di-tert-butylphosphine borane

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About This Item

Empirical Formula (Hill Notation):
C8H19P · BH3
CAS Number:
Molecular Weight:
160.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
Assay:
97%
Form:
solid
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InChI

1S/C8H19P.BH3/c1-7(2,3)9-8(4,5)6;/h9H,1-6H3;1H3

SMILES string

B.CC(C)(C)PC(C)(C)C

InChI key

JPINHYFOWCBINQ-UHFFFAOYSA-N

assay

97%

form

solid

reaction suitability

reagent type: reductant

mp

59-64 °C

functional group

phosphine

Application

Reactant for:
  • Preparation of N-heterocyclic carbene borane complexes by Lewis base exchange reactions
  • Dehydrocoupling reactions
  • Tele-substitution reactions on fluorobenzenechromium complexes
  • Palladium-catalyzed biaryl-coupling reactions
  • Palladium-catalyzed Suzuki coupling

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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