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692182

(R)-Ru(OAc)2(DM-SEGPHOS®)

Synonym(s):

Diacetato[(R)-5,5′-bis[di(3,5-xylyl)phosphino]-4,4′-bi-1,3-benzodioxole]ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):
C50H50O8P2Ru
Molecular Weight:
941.94
NACRES:
NA.22
PubChem Substance ID:
329761472
UNSPSC Code:
12352005
MDL number:
MFCD09753025
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form

powder

Quality Segment

100

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

functional group

phosphine

storage temp.

2-8°C

SMILES string

CC(=O)O[Ru]OC(C)=O.Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3ccc4OCOc4c3-c5c6OCOc6ccc5P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8

InChI

1S/C46H44O4P2.2C2H4O2.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;2*1-2(3)4;/h9-24H,25-26H2,1-8H3;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

ACKYBTAGKAINOG-UHFFFAOYSA-L

Application

Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
  • Stereoselective preparation of β-amino amides via ruthenium segphos complex-catalyzed asymmetric reductive amination of β-keto amides

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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