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692255

RuCl₂[(R)−DM−BINAP][(R)−DAIPEN]

Name: RuCl2[(R)−DM−BINAP][(R)−DAIPEN]
Brand: ALDRICH

Synonym(s):

Dichloro[(R)−2,2′−bis[di(3,5−xylyl)phosphino]−1,1′−binaphthyl][(2R)−1,1−bis(4−methoxyphenyl)−3−methyl−1,2−butanediamine]ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):

C₇₁H₇₄Cl₂N₂O₂P₂Ru

CAS Number:

220114-32-9

Molecular Weight:

1221.28

MDL number:

MFCD09753026

UNSPSC Code:

12352101

PubChem Substance ID:

329761478

NACRES:

NA.22

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Properties

form

powder

Quality Segment

100

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

mp

197-211 °C

storage temp.

2-8°C

SMILES string

COc1ccc(cc1)C2([NH2][Ru]3(Cl)(Cl)([NH2][C@@H]2C(C)C)[PH](c4cc(C)cc(C)c4)(c5cc(C)cc(C)c5)c6ccc7ccccc7c6-c8c(ccc9ccccc89)[PH]3(c%10cc(C)cc(C)c%10)c%11cc(C)cc(C)c%11)c%12ccc(OC)cc%12

InChI

1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/t;18-;;;/m.1.../s1

InChI key

VMSNEARTLSFOHB-OEGAAENXSA-N

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst for:

Noyori-type enantioselective ketone hydrogenation
Enantioselective and asymmetric hydrogenation of ketones

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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