Key Documents

View All Documentation

692301

RuCl₂[(R)−DM−BINAP][(R,R)−DPEN]

Name: RuCl2[(R)−DM−BINAP][(R,R)−DPEN]
Brand: ALDRICH

Synonym(s):

Dichloro[(R)−2,2′−bis[di(3,5−xylyl)phosphino]−1,1′−binaphthyl][(1R,2R)−1,2−diphenylethylenediamine]ruthenium(II)

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):

C₆₆H₆₄Cl₂N₂P₂Ru

CAS Number:

220114-38-5

Molecular Weight:

1119.15

NACRES:

NA.22

PubChem Substance ID:

329761481

UNSPSC Code:

12352005

MDL number:

MFCD09753028

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

form

powder

Quality Segment

100

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

functional group

amine, phenyl, phosphine

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10

InChI

1S/C52H48P2.C14H16N2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-32H,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1

InChI key

HYMSONXJNGZZBM-ODQAEMFESA-L

Description

General description

The product is a bis-naphthalene containing phosphine ligand, in conjugation with a ruthenium complex.

Application

RuCl₂[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols.

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

新产品

This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Bifunctional transition metal-based molecular catalysts for asymmetric syntheses.

Ikariya T, et al.

Organic & Biomolecular Chemistry, 4(3), 393-406 (2006)

Global Trade Item Number

SKU	GTIN
692301-100MG	04061832624716
692301-50MG	04061832624723