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692328

RuCl₂[(R)-DM-SEGPHOS^® ][(R)-DAIPEN]

Name: RuCl2[(R)-DM-SEGPHOS® ][(R)-DAIPEN]
Brand: ALDRICH

Synonym(s):

Dichloro[(R)-5,5′-bis[di(3,5-xylyl)phosphino]-4,4′-bi-1,3-benzodioxole][(2R)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):

C₆₅H₇₀Cl₂N₂O₆P₂Ru

CAS Number:

944450-43-5

Molecular Weight:

1209.18

NACRES:

NA.22

PubChem Substance ID:

329761482

UNSPSC Code:

12352005

MDL number:

MFCD10567024

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Properties

form

powder

Quality Level

100

functional group

amine, phosphine

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.COc1ccc(cc1)C(N)([C@H](N)C(C)C)c2ccc(OC)cc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10

InChI

1S/C46H44O4P2.C19H26N2O2.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-24H,25-26H2,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/q;;;;+2/p-2/t;18-;;;/m.1.../s1

InChI key

UDSABKQFPIPYOT-OEGAAENXSA-L

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136 JP Application No. 19970359654

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number

MKCG5527

MKBQ0421V

04025LH

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Global Trade Item Number

SKU	GTIN
692328-50MG	04061833056110
692328-100MG	04061833056103