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692379

(R)-DM-BINAP

Name: (<I>R</I>)-DM-BINAP
Brand: ALDRICH

Synonym(s):

(R)-(+)-1,1′-Binaphthalene-2,2′-diyl)bis[bis(3,5-dimethylphenyl)phosphine], (R)-(+)-2,2′-Bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl

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About This Item

Empirical Formula (Hill Notation):

C₅₂H₄₈P₂

CAS Number:

137219-86-4

Molecular Weight:

734.89

UNSPSC Code:

12352005

PubChem Substance ID:

329761489

NACRES:

NA.22

MDL number:

MFCD01630821

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Properties

form

solid

Quality Segment

100

optical activity

[α]20/D +169°, c = 1 in chloroform

reaction suitability

reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Noyori Asymmetric Hydrogenation

mp

187-191 °C

functional group

phosphine

SMILES string

P(c8cc(cc(c8)C)C)(c7cc(cc(c7)C)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5cc(cc(c5)C)C)c4cc(cc(c4)C)C)cccc3

InChI

1S/C52H48P2/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46/h9-32H,1-8H3

InChI key

MXGXXBYVDMVJAO-UHFFFAOYSA-N

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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