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692433

(R)-[(RuCl(BINAP))₂(μ-Cl)₃[NH₂Me₂]

Name: (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2]
Brand: ALDRICH

Synonym(s):

Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]diruthenate(II)

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About This Item

Linear Formula:

(CH₃)₂NH₂+[C₈₈H₆₄Cl₅P₄Ru₂]-

CAS Number:

199684-47-4

Molecular Weight:

1670.84

UNSPSC Code:

12352005

PubChem Substance ID:

329761496

NACRES:

NA.22

MDL number:

MFCD09753033

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Properties

form

powder

Quality Segment

100

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

functional group

amine, phosphine

storage temp.

2-8°C

SMILES string

[Ru-]%18%17[Cl+][Ru-]([Cl+]%18)[Cl+]%17.P(c%16ccccc%16)(c%15ccccc%15)c9c(c%14c(cc9)cccc%14)c%10c%11c(ccc%10P(c%13ccccc%13)c%12ccccc%12)cccc%11.P(c8ccccc8)(c7ccccc7)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5ccccc5)c4ccccc4)cccc3.[Cl-].Cl.N(C)C

InChI

1S/2C44H32P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-32H;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1

InChI key

FRRCROPKBKLCMQ-UHFFFAOYSA-M

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for reseach purposes only. JP Application No. 19960232650

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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