692468
(R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2]
Synonym(s):
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2′-bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl]diruthenate(II)
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About This Item
InChI
1S/2C52H48P2.C2H7N.2ClH.3Cl.2Ru/c2*1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-3-2;;;;;;;/h2*9-32H,1-8H3;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1
SMILES string
Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10.Cc%11cc(C)cc(c%11)P(c%12cc(C)cc(C)c%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17cc(C)cc(C)c%17)c%18cc(C)cc(C)c%18
InChI key
LGSCCUXQQTYWAH-UHFFFAOYSA-M
form
powder
storage temp.
2-8°C
Legal Information
signalword
Warning
hcodes
pcodes
Hazard Classifications
Flam. Sol. 2
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Articles
Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
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