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692468

(R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2]

Synonym(s):

Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2′-bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl]diruthenate(II)

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About This Item

Linear Formula:
(CH3)2NH2+[C104H96Cl5P4Ru2]-
CAS Number:
944451-08-5
Molecular Weight:
1895.27
NACRES:
NA.22
PubChem Substance ID:
329761499
UNSPSC Code:
12352005
MDL number:
MFCD09753035
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form

powder

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

storage temp.

2-8°C

SMILES string

Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10.Cc%11cc(C)cc(c%11)P(c%12cc(C)cc(C)c%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17cc(C)cc(C)c%17)c%18cc(C)cc(C)c%18

InChI

1S/2C52H48P2.C2H7N.2ClH.3Cl.2Ru/c2*1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-3-2;;;;;;;/h2*9-32H,1-8H3;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1

InChI key

LGSCCUXQQTYWAH-UHFFFAOYSA-M

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for reseach purposes only. JP Registration No. 3445074

pictograms

Flame
GHS02

signalword

Warning

hcodes

H228

pcodes

P210

Hazard Classifications

Flam. Sol. 2

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBW2572V
02803MH

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Global Trade Item Number

SKUGTIN
692468-50MG04061832624860
692468-100MG04061832624853