694746
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine
solid
Synonym(s):
P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride
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About This Item
Product Name
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine,
form
solid
Quality Segment
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp
25-29 °C
functional group
phosphine
SMILES string
FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F
InChI
1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H
InChI key
DFZQEHBNAJGDCT-UHFFFAOYSA-N
Application
- Chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation
- Ligands for palladium-catalyzed stereoselective allylation reactions
- Ligands for enantioselective hydrogenations
- Josiphos analog as catalyst for asymmetric hydrogenation
- Ligands used in asymmetric hydrovinylation reactions
Reactant for enantioselective hydrogenation reactions catalyzed by Ru-(phosphine-oxazoline) complexes
Signal Word
Danger
Hazard Codes
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Precautionary Statements
Hazard Classifications
Skin Corr. 1B - Water-react. 3
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