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696307

Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)

greener alternative

Greener Alternative

powder

Synonym(s):

[(iPr)CuCl], [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) chloride

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About This Item

Empirical Formula (Hill Notation):
C27H36ClCuN2
CAS Number:
578743-87-0
Molecular Weight:
487.59
UNSPSC Code:
12161600
PubChem Substance ID:
329761816
NACRES:
NA.22
MDL number:
MFCD09264276
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Product Name

Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I),

form

powder

Quality Segment

100

reaction suitability

core: copper, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C

greener alternative category

Aligned

SMILES string

CC(C)c1cccc(C(C)C)c1N2C=CN(\C2=[Cu]\Cl)c3c(cccc3C(C)C)C(C)C

InChI

1S/C27H36N2.ClH.Cu/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;1H;/q;;+1/p-1

InChI key

JPUFNIIPFXQOCB-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This N-heterocyclic carbene ligand with bulky 2,6-diisopropylphenyl substituents is used for palladium-catalyzed Suzuki-Miyaura and Buchwald-Hartwig coupling reactions. Its strong ς-donor character stabilizes low-valent palladium intermediates while steric bulk promotes reductive elimination, enabling efficient coupling across diverse substrates, thus aligning with Green Chemistry principle "Catalysis". Click here for more information.

Application

"Use for reduction of olefin and carbonyl, carbene transfer reaction, aziridination of olefins, and methyleneation of aldehydes."

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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