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696730

(1S,1′S,2R,2′R)-DuanPhos

Name: (1S,1′S,2R,2′R)-DuanPhos
Brand: ALDRICH

Synonym(s):

(1S,1′S,2R,2′R)-2,2′-Di-tert-butyl-2,3,2′,3′-tetrahydro-1H,1′H(1,1′)biisophosphindolyl

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About This Item

Empirical Formula (Hill Notation):

C₂₄H₃₂P₂

CAS Number:

795290-34-5

Molecular Weight:

382.46

NACRES:

NA.22

PubChem Substance ID:

329761857

UNSPSC Code:

12352005

MDL number:

MFCD11045432

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Properties

form

solid

mp

215-226 °C

SMILES string

[H][C@]([C@@]1([H])[P@](C(C)(C)C)CC2=C1C=CC=C2)([P@](C(C)(C)C)C3)C4=C3C=CC=C4

InChI

1S/C24H32P2/c1-23(2,3)25-15-17-11-7-9-13-19(17)21(25)22-20-14-10-8-12-18(20)16-26(22)24(4,5)6/h7-14,21-22H,15-16H2,1-6H3/t21-,22-,25+,26+/m0/s1

InChI key

HCBRTCFUVLYSKU-CNXCYTMISA-N

Description

Application

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Ligand in rhodium-catalyzed ketone hydroacylation
Cocatalyst for highly selective rhodium-catalyzed conjugate addition reactions of 4-oxobutenamides with arylboronic acids

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Global Trade Item Number

SKU	GTIN
696730-100MG	04061832987507