696730
(1S,1′S,2R,2′R)-DuanPhos
Synonym(s):
(1S,1′S,2R,2′R)-2,2′-Di-tert-butyl-2,3,2′,3′-tetrahydro-1H,1′H(1,1′)biisophosphindolyl
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About This Item
InChI
1S/C24H32P2/c1-23(2,3)25-15-17-11-7-9-13-19(17)21(25)22-20-14-10-8-12-18(20)16-26(22)24(4,5)6/h7-14,21-22H,15-16H2,1-6H3/t21-,22-,25+,26+/m0/s1
SMILES string
[H][C@]([C@@]1([H])[P@](C(C)(C)C)CC2=C1C=CC=C2)([P@](C(C)(C)C)C3)C4=C3C=CC=C4
InChI key
HCBRTCFUVLYSKU-CNXCYTMISA-N
form
solid
mp
215-226 °C
Application
- Ligand in rhodium-catalyzed ketone hydroacylation
- Cocatalyst for highly selective rhodium-catalyzed conjugate addition reactions of 4-oxobutenamides with arylboronic acids
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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