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697257

Copper(I) cyanide di(lithium chloride) complex solution

in anhydrous tetrahydrofuran, liquid

Synonym(s):

Copper(I) cyanide di(lithium chloride)

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About This Item

Linear Formula:
CuCN · 2LiCl
Molecular Weight:
174.35
UNSPSC Code:
12161600
PubChem Substance ID:
329761902
NACRES:
NA.22
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Product Name

Copper(I) cyanide di(lithium chloride) complex solution, in anhydrous tetrahydrofuran

form

liquid

Quality Segment

100

reaction suitability

core: copper, reagent type: catalyst

concentration

in anhydrous tetrahydrofuran

density

0.999 g/mL at 25 °C

SMILES string

[Li]Cl.[Li]Cl.[Cu]C#N

InChI

1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2

InChI key

QGXKBLXNBYNHBV-UHFFFAOYSA-L

Application

Copper(I) cyanide di(lithium chloride) complex can be used for the synthesis of organocopper(I) reagents by transmetalation with organozinc and Grignard reagents. It is also a useful precursor to prepare organocuprate(I) reagents.

signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

flash_point_f

1.4 °F - closed cup - Solvent

flash_point_c

-17 °C - closed cup - Solvent

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

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