69893
2-Morpholinoethyl isocyanide
≥98.0% (GC)
Synonym(s):
4-(2-Isocyanoethyl)morpholine, MEI
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About This Item
Empirical Formula (Hill Notation):
C7H12N2O
CAS Number:
Molecular Weight:
140.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4666990
Assay:
≥98.0% (GC)
Form:
liquid
Quality Level
assay
≥98.0% (GC)
form
liquid
refractive index
n20/D 1.469
bp
72-73 °C/0.7 mmHg (lit.)
density
1.017 g/mL at 20 °C (lit.)
functional group
amine, ether, isonitrile
storage temp.
−20°C
SMILES string
[C-]#[N+]CCN1CCOCC1
InChI
1S/C7H12N2O/c1-8-2-3-9-4-6-10-7-5-9/h2-7H2
InChI key
MFRZPLYKVDHOSN-UHFFFAOYSA-N
Application
2-Morpholinoethyl isocyanide can be used for the synthesis of:
It can also be used as a ligand in bis-cyclometalated iridium complexes for the organic light emitting diodes (OLEDs).
- Nitrogen acyclic carbene (NAC) complexes to be used as catalysts for the synthesis of phenol and hydration of alkynes.
- Variety of imidazo[1,2-a]pyridines and α-acylaminoamides by Ugi condensation reaction.
- 2-Aminobenzoxazoles and 3-aminobenzoxazines having important therapeutic activities.
It can also be used as a ligand in bis-cyclometalated iridium complexes for the organic light emitting diodes (OLEDs).
Other Notes
Potent coupling reagent for peptide synthesis giving higher yields and less racemization than DCCI; Reagent used in a Passerini-like reaction to alpha-hydroxy amides
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Nature, 578(7793), 82-93 (2020-02-07)
Cancer is driven by genetic change, and the advent of massively parallel sequencing has enabled systematic documentation of this variation at the whole-genome scale1-3. Here we report the integrative analysis of 2,658 whole-cancer genomes and their matching normal tissues across 38
J.-L. Fauchere
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New and Easily Accessible Nitrogen Acyclic Gold (I) Carbenes: Structure and Application in the Gold-Catalyzed Phenol Synthesis as well as the Hydration of Alkynes.
Hashmi ASK, et al.
Advanced Synthesis & Catalysis, 352(8), 1315-1337 (2010)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 69893-50ML | 04061838136435 |
| 69893-10ML | 04061832794808 |