699616
氯[三(2,4-二叔丁基苯基)亚磷酸]金
powder
别名:
[三(2,4-二叔丁基苯基)亚磷酸]氯化金
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关于此项目
经验公式（希尔记法）:
C42H63AuClO3P
化学文摘社编号:
分子量:
879.34
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
氯[三(2,4-二叔丁基苯基)亚磷酸]金,
form
powder
Quality Segment
reaction suitability
core: gold, reagent type: catalyst
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
200-202 °C
greener alternative category
SMILES string
Cl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C
InChI
1S/C42H63O3P.Au.ClH/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;;/h19-27H,1-18H3;;1H/q;+1;/p-1
InChI key
GCWCLHMEYZKZRO-UHFFFAOYSA-M
General description
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a cationic Au(I) complex derived from chlorotris(2,4-di-tert-butylphenyl)phosphitegold that catalyzes regioselective 1,3-transposition of ynones. Click here for more information.
Application
Gold Catalysts — 21st Century ′Gold Rush′
- Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes
Catalyst for:
- [4C+2C] cycloadditions
- Cis-selective single-cleavagte skeletal cycloisomerization
- Diastereoselective Au-catalyzed intermolecular cyclopropanation
- Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes
- Addition reactions
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves