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700223

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)

97%, crystals

Synonym(s):

Mn(dpm)3, Shenvi Hydrogenation Catalyst, Mn(TMHD)3, Tris(dipivaloylmethanato)manganese

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About This Item

Linear Formula:
Mn(C11H19O2)3
CAS Number:
14324-99-3
Molecular Weight:
604.74
UNSPSC Code:
12161600
PubChem Substance ID:
329762189
NACRES:
NA.22
MDL number:
MFCD00269825
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Product Name

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 97%

Quality Level

100

assay

97%

form

crystals

reaction suitability

core: manganese, reagent type: catalyst

mp

160-170 °C

SMILES string

CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI

1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;

InChI key

ORZPLLPBZHORSD-LWTKGLMZSA-K

Application

Catalyst for:
  • Intramolecular Diels-Alder reactions
  • Single electron donor for excess electron transfer studies in DNA
  • Enantioselective synthesis
  • Borylation reactions
  • Hydrohydrazination and hydroazidation
  • Oxidative carbonylation of phenol
Notably, this non-precious metal catalyst can be used to obtain the thermodynamic hydrogenation product of olefins, selectively.

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX6629
MKCP6170
MKCN2290
MKCM1390
MKCK7540

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Global Trade Item Number

SKUGTIN
700223-1G04061832795409