700665
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
Synonym(s):
(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
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About This Item
InChI
1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
SMILES string
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
InChI key
BVICVEIKBNVROI-UHFFFAOYSA-N
form
solid
optical activity
[α]22/D −44.0°, c = 1 in DMSO
mp
390-400 °C
functional group
phosphate
storage temp.
−20°C
Quality Level
Related Categories
Application
- Asymmetric hydrogenation cascade
- Enantioselective Friedel-Crafts reaction
- Asymmetric hydrogenation of 2-substituted quinolines
- Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
- Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
- Asymmetric transfer hydrogenation of substituted quinoxalines
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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