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Merck
CN

700703

N-tert-Butyl-N-(2-methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylamine

Synonym(s):

2,2,5-Trimethyl-3-(1-phenylethoxy)-4-phenyl-3-azahexane, Alkoxyamine NMP initiator

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About This Item

Empirical Formula (Hill Notation):
C22H31NO
CAS Number:
Molecular Weight:
325.49
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
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InChI

1S/C22H31NO/c1-17(2)21(20-15-11-8-12-16-20)23(22(4,5)6)24-18(3)19-13-9-7-10-14-19/h7-18,21H,1-6H3

SMILES string

CC(C)C(N(OC(C)c1ccccc1)C(C)(C)C)c2ccccc2

InChI key

FPFRTDOMIFBPBZ-UHFFFAOYSA-N

form

liquid

refractive index

n20/D 1.536

density

0.968 g/mL at 25 °C

storage temp.

−20°C

Quality Level

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Benoit, D., Chaplinski, V., Braslau, R., Hawker, C.J.
Journal of the American Chemical Society, 121, 3904-3904 (1999)

Articles

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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