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Merck
CN

701475

Dichloro[(2,6,10-dodecatriene)-1,12-diyl]ruthenium(IV)

powder

Synonym(s):

Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV), Dichloro-2,6,10-dodecatrienylene-ruthenium, Dichloro[(1,2,3,6,7,10,11,12-η)-2,6,10-dodecatriene-1,12-diyl]-ruthenium

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About This Item

Empirical Formula (Hill Notation):
C12H18Cl2Ru
CAS Number:
Molecular Weight:
334.25
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Dichloro[(2,6,10-dodecatriene)-1,12-diyl]ruthenium(IV),

SMILES string

Cl[Ru]1(Cl)C\C=C\CCC=CCC\C=C\C1

InChI

1S/C12H18.2ClH.Ru/c1-3-5-7-9-11-12-10-8-6-4-2;;;/h3-6,11-12H,1-2,7-10H2;2*1H;/q;;;+2/p-2/b5-3+,6-4+,12-11-;;;

InChI key

RSRAKQPWMXANGM-LXALEWKWSA-L

form

powder

reaction suitability

core: ruthenium, reagent type: catalyst

mp

190 °C

Quality Level

Application

Catalyst for:
  • Redox isomerization/transfer hydrogenation
  • Deprotection of N-allyl amides and lactams
  • Isomerization of allylamines
  • Isomerization of allylic alcohols into carbonyl compounds
Catalysts used in the deprotection of N-allyl amides and lactams

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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