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701629

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

Name: Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate
Brand: ALDRICH

97%, powder

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About This Item

Empirical Formula (Hill Notation):

C₁₆H₂₄F₆RhSb

CAS Number:

130296-28-5

Molecular Weight:

555.02

UNSPSC Code:

12161600

PubChem Substance ID:

329762310

NACRES:

NA.22

MDL number:

MFCD11113031

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Properties

Product Name

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate, 97%

Quality Segment

100

assay

97%

form

powder

reaction suitability

reagent type: catalyst
core: rhodium, core: rhodium

mp

58-60 °C

storage temp.

−20°C

SMILES string

[Rh+].F[Sb-](F)(F)(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.6FH.Rh.Sb/c2*1-2-4-6-8-7-5-3-1;;;;;;;;/h2*1-2,7-8H,3-6H2;6*1H;;/q;;;;;;;;+1;+5/p-6/b2*2-1-,8-7-;;;;;;;;

InChI key

BROZUPPJWNODCU-SXGOCSEPSA-H

Description

Application

Catalyst for:

[3+2] Cycloaddition
Preparation of diastereomeric chiral phosphorus mon- and bidentate diamidophosphite ligands based on dianydromannitol and their use in asymmetric metallocomplex catalysis
C-C bond-forming hydrogenation

Pictograms

GHS07,GHS09

Signal Word

Warning

Hazard Codes

H302 + H332,H411

Precautionary Statements

P261 - P264 - P271 - P273 - P301 + P312 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves, type N95 (US)

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