Skip to Content
Merck
CN

Key Documents

View All Documentation

703206

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II)

Synonym(s):

Greatcell Solar®, N-3 dye

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C26H16N6O8RuS2
CAS Number:
141460-19-7
Molecular Weight:
705.64
NACRES:
NA.23
PubChem Substance ID:
329762438
UNSPSC Code:
12352103
MDL number:
MFCD11042213
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

assay

95% (NMR)

Quality Level

200

form

powder

mp

>300 °C

λmax

534, 395, 312 nm (lit.)

SMILES string

S=C=N[Ru]N=C=S.OC(=O)c1ccnc(c1)-c2cc(ccn2)C(O)=O.OC(=O)c3ccnc(c3)-c4cc(ccn4)C(O)=O

InChI

1S/2C12H8N2O4.2CNS.Ru/c2*15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h2*1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2

InChI key

VMISXESAJBVFNH-UHFFFAOYSA-N

General description

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II) (N3 dye) is a ruthenium polypyridyl based complex that can be used as a sensitizer. It is a highly stable polymer in which the photocurrent decreases with an increase in the concentration of N3 dye.

Application

N3 dye can be coated on electrodes for improving the sensitivity of the dye sensitized solar cells (DSSCs) which can further enhance the power conversion efficiency (PCE).
Efficent DSSCs for Direct Conversion of Sunlight to Electricity

Legal Information

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar Materials Pty Ltd.
Dyesol is a registered trademark of Greatcell Solar

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCV7283
MKCT4495
MKCQ2080
MKCK9501
MKCJ3097

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

ZnO Aggregates in Dye-Sensitized Solar Cells

Operation principle and market dominance of single crystalline silicon solar cells.

Efficient dye-sensitized solar cells for direct conversion of sunlight to electricity

Dye-sensitized solar cells directly convert sunlight to electricity

Optoelectronic Devices with DPP-containing Molecules

Organic materials in optoelectronic devices like LEDs and solar cells are of significant academic and commercial interest.

View All Articles
Ruthenium (II) Charge-Transfer Sensitizers Containing 4, 4 `-Dicarboxy-2, 2 `-bipyridine. Synthesis, Properties, and Bonding Mode of Coordinated Thio-and Selenocyanates
Kohle O, et al.
Inorganic Chemistry, 35(16), 4779-4787 (1996)
Stark effects after excited-state interfacial electron transfer at sensitized TiO2 nanocrystallites
Ardo S, et al.
Journal of the American Chemical Society, 132(19), 6696-6709 (2010)
Transport-limited recombination of photocarriers in dye-sensitized nanocrystalline TiO2 solar cells
Kopidakis N, et al.
The Journal of Physical Chemistry B, 107(41), 11307-11315 (2003)
View All Related Papers

Global Trade Item Number

SKUGTIN
703206-1G04061826241929