703486
sec-Butylmagnesium chloride lithium chloride complex solution
1.2 M in THF
Synonym(s):
2-Butylmagnesium chloride lithium chloride complex, Turbo Grignard
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About This Item
SMILES string
[Li]Cl.CCC(C)[Mg]Cl
InChI
1S/C4H9.2ClH.Li.Mg/c1-3-4-2;;;;/h3H,4H2,1-2H3;2*1H;;/q;;;2*+1/p-2
InChI key
ZMDHAYOBNXOYEU-UHFFFAOYSA-L
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
1.2 M in THF, 14 % (w/w)
density
0.973 g/mL at 25 °C
Application
Legal Information
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
-6.7 °F
flash_point_c
-21.5 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Articles
Salt additives increase both the rate and the efficiency of the Mg-halogen exchange reaction. The most effective reagents are generated with R-MgCl (R = i-Pr, s-Butyl) and 1.0 equiv of LiCl.
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