Key Documents

View All Documentation

703915

RuCl(p-cymene)[(S,S)-Ts-DPEN]

Name: RuCl(p-cymene)[(S,S)-Ts-DPEN]
Brand: ALDRICH

Synonym(s):

[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):

C₃₁H₃₅ClN₂O₂RuS

CAS Number:

192139-90-5

Molecular Weight:

636.21

NACRES:

NA.22

PubChem Substance ID:

329762076

UNSPSC Code:

12352116

MDL number:

MFCD14155881

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

form

solid

Quality Segment

100

optical activity

[α]20/D +178°, c = 0.5 in chloroform

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

mp

>175 °C

functional group

amine, phenyl

storage temp.

2-8°C

SMILES string

CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4

InChI

1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1

InChI key

AZFNGPAYDKGCRB-XCPIVNJJSA-M

Description

General description

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst involved in:

Asymmetric transfer hydrogenation of imines and ketones
Intramolecular asymmetric reductive amination
Tandem hydroformylation / hydrogenation of terminal olefins

Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

Legal Information

Sold in collaboration with Takasago for research purposes only. WO9720789

Still not finding the right product?

Explore all of our products under RuCl(p-cymene)[(S,S)-Ts-DPEN]

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library