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708674

RuCl[(S,S)-TsDPEN](mesitylene)

Name: RuCl[(<I>S</I>,<I>S</I>)-TsDPEN](mesitylene)
Brand: ALDRICH

95%, solid

Synonym(s):

[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium

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About This Item

Empirical Formula (Hill Notation):

C₃₀H₃₃ClN₂O₂RuS

CAS Number:

174813-81-1

Molecular Weight:

622.18

UNSPSC Code:

12161600

PubChem Substance ID:

329762816

NACRES:

NA.22

MDL number:

MFCD12545952

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Properties

Product Name

RuCl[(S,S)-TsDPEN](mesitylene), 95%

Quality Level

100

assay

95%

form

solid

mp

241-249 °C

storage temp.

2-8°C

SMILES string

Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4

InChI

1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1

InChI key

XBNBOGZUDCYNOJ-XCPIVNJJSA-M

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only. WO9720789

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Global Trade Item Number

SKU	GTIN
708674-500MG	04061833500477
708674-100MG	04061833500460