Key Documents

View All Documentation

708682

RuCl[(R,R)-TsDPEN](mesitylene)

Name: RuCl[(<I>R</I>,<I>R</I>)-TsDPEN](mesitylene)
Brand: ALDRICH

90%

Synonym(s):

[N-[(1R,2R)-2-(Amino-κN)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro [(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):

C₃₀H₃₃ClN₂O₂RuS

CAS Number:

174813-82-2

Molecular Weight:

622.18

NACRES:

NA.22

PubChem Substance ID:

329762817

UNSPSC Code:

12352116

MDL number:

MFCD12545951

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

Quality Segment

100

assay

90%

form

solid

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

mp

241-249 °C

functional group

amine, phenyl

storage temp.

2-8°C

SMILES string

Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4

InChI

1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1

InChI key

XBNBOGZUDCYNOJ-AGEKDOICSA-M

Description

Application

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

(2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only. WO9720789

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library